Friends alum Jennifer Aniston rocked a snug pair of black leather pants in Hollywood to pre-tape her appearance on Wednesday night’s episode of Jimmy Kimmel Live! The Golden Globe winner paired her edgy trousers with dark purple combat boots, a simple black T-shirt, and a maxi-peacoat selected by stylist Ryan Hastings.

Hairstylist Chris McMillan coiffed the San Fernando Valley native’s signature flaxen locks for her 10th appearance on the ABC late night show, which also features guests Chris Elliott and Rita Ora. Jennifer also prominently held up a bottle of Glaceau SmartWater, the Coca-Cola-owned mineral water company she’s been brand ambassador for since 2007.

Coincidentally, Aniston’s estranged second husband Justin Theroux had just appeared on Kimmel Tuesday night where he said he sometimes gets mistaken for Canadian Prime Minister Justin Trudeau on social media.In February, TMZ discovered that the acting couple’s 2015 wedding at their shared Bel-Air mansion might not have been technically legal, so no formal divorce is needed.

When Extra asked the Emirates Airline spokesmodel about ‘seeking treatment’ after separating from the SAG Award nominee a year ago, she cracked: ‘I’ve been in therapy for years.’